I really applaud you for coming out, I know it has to be really difficult for you. I completely respect you for that, and I'm sure the MUG community will be nothing but supportive.
Daantje is full of great advice. I think the most important thing is the eyebrows. I personally never leave the house without my eyebrows defined. They really frame the face. What I use everyday is just a brow powder and apply it with an angled brush.
The lashes is another good point. You might want to stick to an eyelash curler and mascara before you tackle lashes.
You will find PLENTY of great, helpful videos out there for anything you need makeup-related.
And I don't know if you've come across this site, but it's a guy helping transgender females with makeup concerns: http://www.chrisspagani.com/gender/makeup.htm
I look forward to hearing about your progress in makeup, and please keep us posted on how you're doing!!